Cyclomagnesation of dienes catalyzed by a chiral ansa-zirconocene
نویسندگان
چکیده
منابع مشابه
Cyclomagnesation of dienes catalyzed by a chiral ansa-zirconocene
The biphenyl-bridged. chiral zirconocene complex rac-2.2' -biphenyl-bis( 3.4-dimethylcyclopentadienyl I zirconium dichloride catalyzes the reaction of 1.6and 1,7 -dienes with excess dibutyl magnesium to bis( butyl-magnesio-methyl '-substituted cycloalkanederivatives. Analogous reactions occur with butyl magnesium chloride and with heteroatom-t.:Ontaining dienes. The preference of 1.6-dienes for...
متن کاملDevelopments of chiral metallocenes as polymerization catalysts.
This review article describes developments in chiral metallocenes as polymerization catalysts focusing on C2 symmetric ansa-zirconocene complexes. Selective synthesis of rac-isomers of ansa-zirconocenes are surveyed. Isospecific polymerizations of propylene catalyzed by chiral zirconocenes are summarized. Advanced series of polymerizations by chiral metallocenes such as asymmetric polymerizatio...
متن کاملTransamidation of primary amides with amines catalyzed by zirconocene dichloride.
Zirconocene dichloride (Cp(2)ZrCl(2)) has been shown to be an effective catalyst for the transamidation of primary amides with amines in cyclohexane at 80 °C in 5-24 hours. For favourable substrates, the reaction can be performed at temperatures as low as 30 °C.
متن کاملFormation of trivalent zirconocene complexes from ansa-zirconocene-based olefin-polymerization precatalysts: an EPR- and NMR-spectroscopic study.
Reduction of Zr(IV) metallocenium cations with sodium amalgam (NaHg) produces EPR signals assignable to Zr(III) metallocene complexes. The chloro-bridged heterodinuclear ansa-zirconocenium cation [(SBI)Zr(μ-Cl)2AlMe2](+) (SBI = rac-dimethylsilylbis(1-indenyl)), present in toluene solution as its B(C6F5)4(-) salt, thus gives rise to an EPR signal assignable to the complex (SBI)Zr(III)(μ-Cl)2AlMe...
متن کاملZirconocene catalyzed diastereoselective carbometalation of cyclobutenes.
The regio- and diastereoselective zirconocene-catalyzed carbomagnesiation of cyclobutenes is herein reported to afford configurationally stable cyclobutylmagnesium species that could subsequently react with a large variety of electrophiles to give polysubstituted cyclobutane species as a single diastereoisomer.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Inorganica Chimica Acta
سال: 1998
ISSN: 0020-1693
DOI: 10.1016/s0020-1693(98)00065-6